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Electrophilic "Fischer Type" Phosphinidene Complexes of Molybdenum, Tungsten, and Ruthenium

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/om010225y
AuthorSearch for: 1; Search for: 1; Search for: 1
Affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
Chloride abstraction from chloroaminophosphido complexes of molybdenum, tungsten, and ruthenium leads to the terminal aminophosphinidene complexes [Cp*(CO)3Mo(=PNiPr2)][AlCl4] (3), [Cp*(CO)3W(=PNiPr2)][AlCl4] (4), and [Cp*Ru(CO)2(=PNiPr2)][AlCl4] (6). These are the first structurally characterized examples of heteroatom-substituted phosphinidene complexes, and 6 is the first example of a late transition metal phosphinidene complex.
Publication date
In
  • Organometallics 20, no. 13 (25 June 2001): 2657–2659.
LanguageEnglish
NPARC number12338589
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Record identifier02f493a3-8abb-497b-8eee-764ce7ff1d24
Record created2009-09-10
Record modified2020-03-27
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