| DOI | Resolve DOI: https://doi.org/10.1002/anie.201300568 |
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| Author | Search for: Yu, Kui1; Search for: Liu, Xiangyang1; Search for: Zeng, Qun; Search for: Leek, Donald M.2; Search for: Ouyang, Jianying1; Search for: Whitmore, Kenneth Matthew1; Search for: Ripmeester, John A.1; Search for: Tao, Ye3; Search for: Yang, Mingli |
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| Affiliation | - National Research Council of Canada. Security and Disruptive Technologies
- National Research Council of Canada. Measurement Science and Standards
- National Research Council of Canada. Information and Communication Technologies
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| Format | Text, Article |
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| Subject | Diphenylphosphine; Feed molar ratio; Low temperature formation; Reproducibilities; Secondary phosphines; Semiconducting nanocrystals; Tri-n-octylphosphine; Coordination reactions; Density functional theory; Molecular modeling; Nanocrystals; Phosphorus compounds; Semiconductor quantum dots; Semiconducting selenium compounds; Phosphine derivative; Chemical structure; Cadmium; Cold Temperature; Models, Molecular; Oleic Acid; Phosphines |
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| Abstract | Getting to the TOP of things: The coordination of tri-n-octylphosphine (TOP) instead of diphenylphosphine (DPP) to cadmium oleate (Cd(OA)2) reveals how tertiary and secondary phosphines enhance the yield and reproducibility of the synthesis of nanocrystals by shifting the equilibrium of the reaction to the right (see picture). High Cd-to-Se and Se-to-TOP feed molar ratios facilitate the formation of Se[DOUBLE BOND]DPP by way of Se exchange from TOP to DPP. |
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| Publication date | 2013-03-25 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21270358 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 08139141-a619-48ac-a62f-0144ec073b95 |
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| Record created | 2014-02-05 |
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| Record modified | 2020-04-22 |
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