| Download | - View accepted manuscript: Gold cluster carbonyls: vibrational spectroscopy of the anions and the effects of cluster size, charge, and coverage on the CO stretching frequency (PDF, 581 KiB)
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| DOI | Resolve DOI: https://doi.org/10.1021/jp055856a |
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| Author | Search for: Fielicke, A.; Search for: vonHelden, G.; Search for: Meijer, G.; Search for: Simard, Benoit1; Search for: Rayner, David1 |
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| Affiliation | - National Research Council Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | We report the vibrational spectra of the carbonyl complexes of anionic gold clusters in the range of the CO stretching frequency as measured in the gas phase using IR multiple photon dissociation spectroscopy. The investigated complexes contain between 3 and 14 Au atoms and up to 7 CO ligands. Special attention is given to the complexes that exhibit saturation CO coverage as well as to the monocarbonyl species. In conjunction with data from the corresponding cationic complexes we quantify how the CO stretching frequency varies with the charge state of the gold cluster. Our results provide a size- and charge-dependent basis to interpret values of the CO stretching frequency measured for CO on deposited gold clusters in terms of the charge states of the clusters. |
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| Publication date | 2005-12-22 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 12330758 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 0853f0e8-561c-4e8e-802f-559311e9f08e |
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| Record created | 2009-09-10 |
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| Record modified | 2020-04-07 |
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