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Generalized Swain-Schaad relations including tunneling and temperature dependence

From National Research Council Canada

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Affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
The Swain-Schaad relation, which relates the kinetic isotope effects of the three hydrogen isotopes, is extended by including tunneling and temperature dependence. The new version shows that the effect of tunneling on theSwain-Schaad exponent is opposite to that usually assumed and depends on the degree of assistance the tunneling receives from other vibrations.
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In
  • Chemical physics letters 410, no. 4-6 (2005): 370–376.
NPARC number12328633
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Record identifier10dae693-de44-489b-a99a-fd59784dcc24
Record created2009-09-10
Record modified2020-04-07
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