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| DOI | Resolve DOI: https://doi.org/10.1021/acsanm.2c05285 |
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| Author | Search for: Bamane, Swapnil S.ORCID identifier: https://orcid.org/0000-0002-7537-1901; Search for: Jakubinek, Michael B.1; Search for: Kanhaiya, KrishanORCID identifier: https://orcid.org/0000-0002-3622-2655; Search for: Ashrafi, Behnam2; Search for: Heinz, HendrikORCID identifier: https://orcid.org/0000-0002-6776-7404; Search for: Odegard, Gregory M.ORCID identifier: https://orcid.org/0000-0001-7577-6565 |
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| Affiliation | - National Research Council of Canada. Security and Disruptive Technologies
- National Research Council of Canada. Aerospace
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| Funder | Search for: Michigan Technological University |
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| Format | Text, Article |
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| Subject | contact angle; surface tension; processibility; compositematerials; aerospacematerials; moleculardynamics |
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| Abstract | Boron nitride nanotubes (BNNTs) are a very promising reinforcement for future high-performance composites because of their excellent thermo-mechanical properties. To take full advantage of BNNTs in composite materials, it is necessary to have a comprehensive understanding of the wetting characteristics of various high-performance resins. Molecular dynamics (MD) simulations provide an accurate and efficient approach to establish the contact angle values of engineering polymers on reinforcement surfaces, which offers a measure for the interaction between the polymer and reinforcement. In this research, MD simulations and experiments are used to determine the wettability of various epoxy systems on BNNT surfaces. The reactive interface force field (IFF-R) is parameterized and utilized in the simulations to accurately describe the interaction of the epoxy monomers with the BNNT surface. The effect of the epoxy monomer type, hardener type, local atomic charges, and temperature on the contact angle is established. The results show that contact angles decrease with increases in temperature for all the epoxy/hardener systems. The bisphenol-A-based epoxy system demonstrates better wettability with the BNNT surface than the bisphenol-F based epoxy system. Furthermore, the MD predictions demonstrate that these observations are validated with experimental results, wherein the same contact angle trends are observed for macroscopic epoxy drops on nonwoven nanotube papers. As wetting properties drive the resin infusion in the reinforcement materials, these results are important for the future manufacturing of high-quality BNNT/epoxy nanocomposites for high-performance applications such as aerospace and aeronautical vehicles. |
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| Publication date | 2023-02-22 |
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| Publisher | American Chemical Society |
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| Language | English |
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| Peer reviewed | Yes |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 201eece7-a1fb-4a23-afe6-ff0b0bf70491 |
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| Record created | 2023-08-24 |
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| Record modified | 2023-08-24 |
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