Vibrational spectroscopy and thermophysical properties of ultralow sulfur diesel: alternative fuel binary blends

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DOI	Resolve DOI: https://doi.org/10.1021/acs.energyfuels.7b02847
Author	Search for: Petrucci, Thiago; Search for: Michaelian, Kirk H.; Search for: Gieleciak, Rafal; Search for: Shen, Jun¹ ; Search for: Zhou, Jianqin¹ ; Search for: Gu, Caikang¹ ; Search for: Neill, W. Stuart¹ ; Search for: Baesso, Mauro L.; Search for: Malacarne, Luis C.; Search for: Astrath, Nelson G. C.
Name affiliation	National Research Council Canada. Energy, Mining and Environment
Format	Text
Type	Article
Journal title	Energy & Fuels
ISSN	0887-0624 1520-5029
Volume	31
Issue	12
Pages	13775–13784
Abstract	Four alternative fuels (AF) were blended with ultralow sulfur diesel (ULSD) at five different proportions (10, 20, 30, 50, and 100 vol % AF) to create 20 binary mixtures in this work. Two renewable jet AFs and two renewable diesel AFs were investigated. Interactions between the components in the mixtures were analyzed by means of spectroscopy (Raman, near-infrared), thermophysical (thermal diffusivity, thermo-optic coefficient), and physical (density) techniques. Correlations among the data were investigated using principal component analysis and partial least-squares regression. Trends in Raman intensities and band positions as well as thermophysical properties showed that the AF/ULSD blends resembled two-component mixtures despite the known complexities of the constituents. Specifically, spectra combined according to the percentages of the components in each mixture; thermophysical and physical properties exhibited similar behavior. The spectra showed strong correlations with all three physical properties, creating the possibility for predicting the properties of similar AF/ULSD mixtures. These properties are governed by the chemical compositions of the fuels.
Publication date	2017-11-28
Publisher	ACS
Terms of use	Permission is granted to temporarily download one copy of the materials for personal, noncommercial transitory viewing only. NRC Publications Archive - Copyright and terms of use
Language	English
Peer reviewed	Yes
NRC number	NRC-EME-55910
NPARC number	23002804
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Record identifier	20891c80-22c2-4dd4-9396-d347b2c50ed2
Record created	2018-03-01
Record modified	2019-03-11

Date modified:: 2019-03-26

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