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Configurational characterization of the 1-(trimethylsilyl)cyclopropyl radical

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1016/S0040-4039(00)85492-1
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Affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
Reductive debromination of 1-bromo-1-(trimethylsilyl)cyclopropane-1-13C produced the labeled radical, the EPR spectrum of which showed a 13C[alpha] = 40.9 G, a H[beta](4H) = 27.0 G, and g = 2.00228, thereby confirming it to be planar, or nearly so.
Publication date
In
  • Tetrahedron Letters 27, no. 4 (1986): 411–414.
LanguageEnglish
Peer reviewedYes
NPARC number12338322
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Record identifier24a2da11-4491-4a65-b331-12c0b613fb3e
Record created2009-09-10
Record modified2023-05-09
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