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Alkyne isomerization reagents: mixed alkali metal amides

From National Research Council Canada

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DOIResolve DOI: https://doi.org/10.1139/v84-224
AuthorSearch for: 1
Affiliation
  1. National Research Council of Canada. NRC Plant Biotechnology Institute
FormatText, Article
Abstract
Addition of sodium and potassium alkoxides, particularly potassium tert-butoxide, to the lithium salts of either 1,2-diaminoethane or 1,3-diaminopropane afford alkyne isomerization reagents that effect triple bond migration to the end of a methylene chain under milder conditions and in higher yield than do previously reported reagents.
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  • Canadian Journal of Chemistry 62, no. 7 (1984): 1333–1334.
LanguageEnglish
Peer reviewedYes
NRC numberNRCC 22965
NPARC number21273770
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Record identifier2c680c7c-bd68-409f-91d5-a149d53cee3b
Record created2015-01-20
Record modified2023-08-31
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