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New approaches to free radical thermochemistry

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1007/BF03156152
AuthorSearch for: ; Search for: 1
Affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
A variety of unusual techniques have been used to measure thermodynamic propeties of free radicals and heats of the reactions in which they participate. These include a radical buffer EPR technique, the appearance energy method, photoacoustic spectroscopy, and electrochemical detection of free radicals. The methods can be applied to systems involving organometallic and high molecular weight materials which are normally inaccessible to conventional, gas phase techniques.
Publication date
In
  • Reviews of Chemical Intermediates 7, no. 1 (June 1986): 31–44.
LanguageEnglish
Peer reviewedYes
NPARC number12339260
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Record identifier34be3b00-f4be-4a03-8030-631ec665247a
Record created2009-09-11
Record modified2023-05-09
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