| DOI | Resolve DOI: https://doi.org/10.1063/1.4813002 |
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| Author | Search for: Siebrand, Willem1; Search for: Smedarchina, Zorka1; Search for: Fernández-Ramos, Antonio |
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| Affiliation | - National Research Council of Canada. Security and Disruptive Technologies
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| Format | Text, Article |
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| Subject | excited levels; ground level; malonaldehyde; selection rules; splittings; tunneling splittings; vibrationally excited; zero-point; excited states |
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| Abstract | Five symmetry-based selection rules are formulated that relate the tunneling splitting of a vibrationally excited level to that of the ground level in molecules with a symmetric double-minimum potential. The rules, which explain why excited levels frequently have smaller splittings than zero-point levels, are used to interpret the observed and calculated splittings in malonaldehyde. |
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| Publication date | 2013-07-08 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21270471 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 370dfbfd-7b62-42a4-88ab-253b57b35912 |
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| Record created | 2014-02-12 |
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| Record modified | 2020-04-22 |
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