| DOI | Resolve DOI: https://doi.org/10.1016/0040-4039(96)01825-4 |
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| Author | Search for: Banks, J.T; Search for: Ingold, K. U.1; Search for: Della, E.W; Search for: Walton, J.C |
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| Affiliation | - National Research Council of Canada
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| Format | Text, Article |
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| Subject | bicyclo compound; cyclopentane derivative; chemical reaction kinetics; drug synthesis; reaction analysis |
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| Abstract | Absolute rate constants for reactions of bicyclo[1.1.1]pent-1-yl radicals with α-methylstyrene (1.4 x 107 M-1s-1) and 1,4-cyclohexadiene (4.6 x 105 M-1s-1) at 25°C were measured by laser flash photolysis. This bridgehead radical is more reactive than tert-butyl which we attribute to its high s-character and the absence of steric shielding of the radical center. |
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| Publication date | 1996 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21276493 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 38fd9043-352b-41e4-a9f0-f517ee7d2af2 |
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| Record created | 2015-10-13 |
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| Record modified | 2020-03-20 |
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