Bis(trifluoromethyl)aminyl and bis(trifluoromethyl) nitroxide

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/j100463a021
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  1. National Research Council of Canada
FormatText, Article
Journal titleThe Journal of Physical Chemistry
ISSN0022-3654
Volume84
Issue26
Pages3597–3599
Abstract
The EPR parameters for (CF3)2N· have been determined to be g = 2.00374, aN = 13.84 G, and aF = 13.84 G in CF2Cl2 from 150 to 220 K. The (CF3)2NO· radical has been generated from (CF3)2Ṅ by using isotopically enriched 17O2. It has a17O equal to 23.6 G which is higher than a17O values found for dialkyl nitroxides (19-20 G). This serves to confirm that (CF3)2NO· has a higher spin density on oxygen than other nitroxides. © 1980 American Chemical Society.
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LanguageEnglish
Peer reviewedYes
NPARC number21276517
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