| Download | - View accepted manuscript: Heck reaction using palladium complexed to dendrimers on silica (PDF, 620 KiB)
|
|---|
| DOI | Resolve DOI: https://doi.org/10.1139/cjc-78-6-920 |
|---|
| Author | Search for: Alper, Howard; Search for: Arya, Prabhat1; Search for: Bourque, S. Christine; Search for: Jefferson, Gary R.; Search for: Manzer, Leo E. |
|---|
| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
|
|---|
| Format | Text, Article |
|---|
| Subject | Dendrimer; Heck; palladium; silica; Heck; palladium; silce |
|---|
| Abstract | Polyamidoamine dendrimers, constructed on the surface of silica, were phosphonated using diphenylphosphinomethanol (prepared in situ) and complexed to form a palladium-dimethyl TMEDA complex. This catalyst was found to be effective in the Heck reaction of aryl bromides with both butyl acrylate and styrene, affording coupling products in moderate to good yields. The heterogeneous palladium catalyst can also be recycled and reused with only moderate reduction in activity. |
|---|
| Publication date | 2000-06-14 |
|---|
| In | |
|---|
| Language | English |
|---|
| NPARC number | 12340940 |
|---|
| Export citation | Export as RIS |
|---|
| Report a correction | Report a correction (opens in a new tab) |
|---|
| Record identifier | 5194fb61-38b5-4088-9bab-581bc28146e5 |
|---|
| Record created | 2009-09-11 |
|---|
| Record modified | 2020-03-26 |
|---|
