| DOI | Resolve DOI: https://doi.org/10.1021/j150653a001 |
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| Author | Search for: Ingold, K. U.1 ; Search for: Nonhebel, D.C.; Search for: Wildman, T.A.1 |
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| Name affiliation | - National Research Council Canada
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| Format | Text |
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| Type | Article |
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| Journal title | The Journal of Physical Chemistry |
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| ISSN | 0022-3654 |
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| Volume | 88 |
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| Issue | 9 |
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| Pages | 1675–1678; # of pages: 4 |
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| Abstract | At low temperatures the PhCMe2CH2CH2 radical preferentially adopts a conformation in which the radical center and the phenyl substituent are gauche to each other when viewed along the Cβ-Cγ bond. The β-hydrogens are magnetically nonequivalent and the magnitudes of their hyperfine splitting represent an average over rotation about the Cα-Cβ bond. On the basis of the equation αHβ= 54〈cos2 θ〉 G, we have derived a simple, two-component rotational potential which supports the suggestion that there is a weak, attractive interaction between the singly occupied Cα 2pz orbital and the π-cloud of the phenyl substituent. The conformations of some related radicals are also discussed. |
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| Publication date | 1984 |
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| Terms of use | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21276773 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction |
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Record identifier | 619ba00c-ad98-4b19-bce1-3c961b387d3e | | Record created | 2015-10-13 |
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| Record modified | 2017-03-23 |
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