| Download | - View accepted manuscript: An AES and SIMS study of the influence of chloride on the passive oxide film on iron (PDF, 809 KiB)
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| Author | Search for: Goetz, R.1; Search for: MacDougall, B.1; Search for: Graham, M. J.1 |
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| Affiliation | - National Research Council of Canada. NRC Institute for Chemical Process and Environmental Technology
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| Format | Text, Article |
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| Abstract | The kinetics of passivation of Fe in pH 8.4 birate buffer solution at 0.0 V have been studied in both the presence and absence of 0.5 M Cl-. Cl- has no influence on the decay of the passive current with time over the course of several hours. Oxide films wer examined by AES and SIMS for possible Cl- incorporation into the oxide lattice. Neither technique was able to detect any Cl- within the film. The same is true even above the pitting potential, which probably indicates that Cl- incorporation into the oxide film is not a precursor to pit initiation. It also appears that Cl- does not cause any film thinning. |
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| Publication date | 1986 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NRC number | NRCC 52289 |
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| NPARC number | 16285585 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 6aa2caa1-9105-419f-80f3-7a73c5ff82e0 |
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| Record created | 2010-11-01 |
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| Record modified | 2020-05-08 |
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