| DOI | Resolve DOI: https://doi.org/10.1021/ic000981g |
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| Author | Search for: Soldatov, D. V.1; Search for: Henegouwen, A. T.1; Search for: Enright, G. D.1; Search for: Ratcliffe, C. I.1; Search for: Ripmeester, J. A.1 |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | Several solid phases of nickel(II) and zinc(II) dibenzoylmethanates (DBMs) have been isolated and studied. Nickel dibenzoylmethanate forms three polymorphic forms and a fourth a clathrate form. A brown form containing [Ni(DBM)2] monomers transforms upon heating into a green form containing [Ni3(DBM)6] trimers. Benzene stabilizes the trimeric structure at room temperature, forming a [Ni3(DBM)6]·2(benzene) inclusion compound. Zinc dibenzoylmethanate has been prepared in two polymorphic forms, containing [Zn(DBM)2] monomers or [Zn2(DBM)4] dimers. |
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| Publication date | 2001-03-26 |
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| In | |
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| Language | English |
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| NPARC number | 12328376 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 6d0e28a0-825b-48b8-9152-e42a0afd8b6c |
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| Record created | 2009-09-10 |
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| Record modified | 2020-03-27 |
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