Distinguishing between abstraction and addition as the first step in the reaction of a nitroxyl radical with cyclohexene

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/ol049527x
AuthorSearch for: 1; Search for: 1
Name affiliation
  1. National Research Council of Canada
FormatText, Article
Subject1,2 dideuteriocyclohexene; cyclohexene derivative; nitrogen derivative; radical; tempol; unclassified drug; abstraction; addition reaction; chemical reaction; methodology
Abstract
An unambiguous method for distinguishing between abstraction-addition and addition-abstraction mechanisms (and mixtures thereof) in the reaction of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl with a specifically deuterated cyclohexene, 1,2-dideuteriocyclohexene, is demonstrated.
Publication date
In
  • Organic Letters 6, no. 10 (2004): 1641–1643.
LanguageEnglish
Peer reviewedYes
NPARC number21276549
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