Distinguishing between abstraction and addition as the first step in the reaction of a nitroxyl radical with cyclohexene

DOI	Resolve DOI: https://doi.org/10.1021/ol049527x
Author	Search for: Coseri, S.¹; Search for: Ingold, K. U.¹
Name affiliation	National Research Council of Canada
Format	Text, Article
Subject	1,2 dideuteriocyclohexene; cyclohexene derivative; nitrogen derivative; radical; tempol; unclassified drug; abstraction; addition reaction; chemical reaction; methodology
Abstract	An unambiguous method for distinguishing between abstraction-addition and addition-abstraction mechanisms (and mixtures thereof) in the reaction of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl with a specifically deuterated cyclohexene, 1,2-dideuteriocyclohexene, is demonstrated.
Publication date	2004
In	Organic Letters 6, no. 10 (2004): 1641–1643.
Language	English
Peer reviewed	Yes
NPARC number	21276549
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Record identifier	7127dac9-229e-4799-a93a-1e1e676f6982
Record created	2015-10-13
Record modified	2020-04-17