Distinguishing between abstraction and addition as the first step in the reaction of a nitroxyl radical with cyclohexene

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/ol049527x
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  1. National Research Council Canada
FormatText
TypeArticle
Journal titleOrganic Letters
ISSN1523-7060
Volume6
Issue10
Pages1641–1643; # of pages: 3
Subject1,2 dideuteriocyclohexene; cyclohexene derivative; nitrogen derivative; radical; tempol; unclassified drug; abstraction; addition reaction; article; chemical reaction; methodology
Abstract
An unambiguous method for distinguishing between abstraction-addition and addition-abstraction mechanisms (and mixtures thereof) in the reaction of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl with a specifically deuterated cyclohexene, 1,2-dideuteriocyclohexene, is demonstrated.
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LanguageEnglish
Peer reviewedYes
NPARC number21276549
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Record identifier7127dac9-229e-4799-a93a-1e1e676f6982
Record created2015-10-13
Record modified2016-05-09
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