| Download | - View accepted manuscript: Production and study of triply charged diatomic ions with femtosecond pulses: Application to Cl₂³⁺ (PDF, 619 KiB)
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| DOI | Resolve DOI: https://doi.org/10.1021/jp003914g |
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| Author | Search for: Verver, R. J.; Search for: Matusek, D. R.; Search for: Wright, J. S.; Search for: Gibson, G. N.; Search for: Bhardwaj, R.1; Search for: Aseyev, S.1; Search for: Villeneuve, D. M.2; Search for: Corkum, P. B.1; Search for: Ivanov, M. Yu1 |
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| Affiliation | - National Research Council Canada. NRC Steacie Institute for Molecular Sciences
- National Research Council Canada. Security and Disruptive Technologies
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| Format | Text, Article |
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| Abstract | We describe the preparation of diatomic trications using intense femtosecond laser pulses, and discuss the feasibility of using femtoseond pump-probe techniques to measure the vibrational spectrum of Cl₂³⁺ . Initial attempts to observe the vibrational spectra of Cl₂³⁺ were unsuccessful. Possible refinements to the experiment are guided by calculations of the electronic states, transition moments, and field-dressed potential curves for Cl₂³⁺ . Solution of the time-dependent Schrödinger equation using these theoretical data as input allow an accurate simulation of pump-probe experiments and their time-delay signals. Optimization of the experimental parameters via the simulation suggests an improved approach to obtaining the spectra of trications, with special emphasis on the unusual aspects of these systems. |
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| Publication date | 2001-03-22 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 12329199 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 77667172-806f-4b66-a460-e34168ef3387 |
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| Record created | 2009-09-10 |
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| Record modified | 2020-03-27 |
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