| DOI | Resolve DOI: https://doi.org/10.1016/j.jms.2007.01.005 |
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| Author | Search for: McKellar, A1; Search for: Tokaryk, D.; Search for: Xu, Li-Hong; Search for: Appadoo, D.; Search for: May, T. |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Subject | Acrolein; Coriolis; Infrared; Propenol; Synchrotron |
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| Abstract | Synchrotron radiation from the new Canadian Light Source facility has been used to obtain a high resolution (0.0012?cm-1) absorption spectrum of acrolein vapor in the 550-660?cm-1 region. Almost 2000 transitions have been included in a detailed analysis of the [nu]12 (~564?cm-1) and [nu]17 (~593?cm-1) fundamental bands which yielded precise values for the band origins, rotational and centrifugal distortion parameters. The analysis included the a- and b-type Coriolis interactions connecting [nu]12 and [nu]17, as well as an a-type Coriolis interaction between [nu]17 and a "dark" perturbing state, identified as 4[nu]18. We believe that this is the first high resolution infrared study of acrolein. |
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| Publication date | 2007-03 |
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| In | |
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| NPARC number | 12328415 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 7b1daf41-93de-43d1-acf8-73d98b33aa45 |
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| Record created | 2009-09-10 |
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| Record modified | 2020-05-10 |
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