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Evidence for reversible ring-opening of the α-cyclopropylbenzyl radical

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/C39900000923
AuthorSearch for: 1; Search for: 1; Search for: 1
Affiliation
  1. National Research Council of Canada
FormatText, Article
Abstract
Kinetic absorption spectroscopy, EPR, and tributylstannane product data indicate that the α-cyclopropylbenzyl radical (1a) undergoes reversible ring-opening to the 4-phenylbut-3-enyl radical (2a) and that equilibrium favours the ring-closed form, (1a).
Publication date
In
  • Journal of the Chemical Society, Chemical Communications, no. 13 (1990): 923–925.
LanguageEnglish
Peer reviewedYes
NPARC number21276651
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Record identifier7beacc14-6b98-4753-ac45-f9cea7176250
Record created2015-10-13
Record modified2020-03-17
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