| DOI | Resolve DOI: https://doi.org/10.1016/j.jms.2018.03.001 |
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| Author | Search for: Barclay, A.J.; Search for: Esteki, K.; Search for: Mckellar, A. R. W.1; Search for: Moazzen-Ahmadi, N. |
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| Affiliation | - National Research Council Canada. Security and Disruptive Technologies
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| Format | Text, Article |
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| Subject | ethylene; spectrum; dimer; trimer; van der waals; infrared; supersonic jet |
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| Abstract | Spectra of ethylene dimers and trimers are studied in the ν11 and (for the dimer) ν9 fundamental band regions of C2H4 (≈2990 and 3100 cm−1) using a tunable optical parametric oscillator source to probe a pulsed supersonic slit jet expansion. The deuterated trimer has been observed previously, but this represents the first rotationally resolved spectrum of (C2H4)3. The results support the previously determined cross-shaped (D2d) dimer and barrel-shaped (C3h or C3) trimer structures. However, the dimer spectrum in the ν9 fundamental region of C2H4 is apparently very perturbed and a previous rotational analysis is not well verified. |
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| Publication date | 2018-03-06 |
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| Publisher | Elsevier |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 23003719 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 7d0fd880-29f5-4782-9277-226bd740056e |
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| Record created | 2018-08-03 |
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| Record modified | 2020-03-16 |
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