| DOI | Resolve DOI: https://doi.org/10.1016/j.cplett.2004.05.098 |
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| Author | Search for: Zgierski, Marek1; Search for: Lim, Edward |
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| Affiliation | - National Research Council Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | Evidence is presented for direct involvement of [pi][sigma]C[6-point triple bond; length half of m-dash]C* state in the intramolecular charge transfer of p-disubstituted diphenylacetylene containing an electron-donating group at one end and an electron-withdrawing group at the other. Comparison of the computed potential energy curves and the experimental transient absorption spectra with the corresponding data for N,N-dimethylaminobenzonitrile (DMABN) suggests that the [pi][sigma]C[6-point triple bond; length half of m-dash]N* state may also play a central role in the photoinduced electron-transfer of DMABN and related molecules. |
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| Publication date | 2004-07-21 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 12328099 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 88c2ce46-6a1c-4e35-b138-0a24d1c3da0a |
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| Record created | 2009-09-10 |
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| Record modified | 2023-06-23 |
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