| DOI | Resolve DOI: https://doi.org/10.1021/ja028303b |
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| Author | Search for: Sanchez-Nieves, Javier1; Search for: Sterenberg, Brian T.1; Search for: Udachin, Konstantin A.; Search for: Carty, Arthur J.1 |
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| Affiliation | - National Research Council Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | The terminal chloroaminophosphido complex [Co(CO)3(PPh3){P(Cl)NiPr2}] is formed via reaction of K[Co(CO)4] with iPr2NPCl2 in the presence of triphenylphosphine. Chloride abstraction by aluminum trichloride leads to the first terminal phosphinidene complex of cobalt, [Co(CO)3(PPh3)(PNiPr2)][AlCl4]. The electrophilicity of the phosphinidene was demonstrated by its reaction with diphenylacetylene to form the phosphirene complex [Co(CO)3(PPh3){P(NiPr2)C(Ph)C(Ph)}][AlCl4]. |
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| Publication date | 2003-02-07 |
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| In | |
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| Language | English |
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| NPARC number | 12338260 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 8aaa95ea-c52c-4e50-8eda-6bd172e6bee5 |
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| Record created | 2009-09-10 |
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| Record modified | 2020-04-02 |
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