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Diethylamido- and pentafluorophenoxo-tungsten(VI) fluorides

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/dt9730001876
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FormatText, Article
Abstract
Tungsten hexafluoride reacts with trimethylsilyldiethylamine or trimethyl(pentafluorophenoxo)silane at or below ambient temperature with the replacement of F by –NEt2 or –OC6F5 groups. Compounds isolated were monomeric WF2(NEt2)4, polymeric WF4(NEt2)2 and monomeric WF5OC6F5. WF4(OC6F5)2 appears to exist in cis- and trans-forms and undergoes reorganisation to give other members of the series.
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In
  • Journal of the Chemical Society, Dalton Transactions, no. 18 (16 February 1973): 1876–1879.
LanguageEnglish
Peer reviewedYes
NRC publication
This is a non-NRC publication

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NPARC number21270326
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Record identifier93a0bd43-ba1c-4e43-85c5-d85af9ecdbe3
Record created2014-01-24
Record modified2020-03-13
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