| DOI | Resolve DOI: https://doi.org/10.1016/j.jssc.2006.07.037 |
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| Author | Search for: Lundgren, Rylan; Search for: Cranswick, Lachlan1; Search for: Bieringer, Mario |
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| Affiliation | - National Research Council of Canada. NRC Canadian Neutron Beam Centre
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| Format | Text, Article |
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| Subject | Bixbyite; Crystal structure; In situ powder X-ray diffraction; InVO3; Magnetism; Powder neutron diffraction; V(III) |
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| Abstract | We report the first synthesis and high-temperature in situ X-ray diffraction study of InVO3. Polycrystalline InVO3 has been prepared via reduction of InVO4 using a carbon monoxide/carbon dioxide buffer gas. InVO3 crystallizes in the bixbyite structure in space group Ia-3 (206) with a=9.80636(31)?? with In3+/V3+ disorder on the (8b) and (24d) cation sites. In situ powder X-ray diffraction experiments and thermal gravimetric analysis in a CO/CO2 buffer gas revealed the existence of the metastable phase InVO3. Bulk samples with 98.5(2)% purity were prepared using low-temperature reduction methods. The preparative methods limited the crystallinity of this new phase to approximately 225(50)??. Magnetic susceptibility and neutron diffraction experiments suggest a spin-glass ground state for InVO3. |
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| Publication date | 2006-12 |
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| In | |
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| NPARC number | 12338913 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 94f3f4a3-3bb0-45b0-96b8-3544acbb7630 |
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| Record created | 2009-09-11 |
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| Record modified | 2020-04-22 |
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