Revised assignment of the electron spin resonance spectrum obtained by photolysis of tetrasulfur tetranitride-bis(norbornene)

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/jo01334a015
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  1. National Research Council Canada
FormatText
TypeArticle
Journal titleJournal of Organic Chemistry
ISSN0022-3263
Volume44
Issue20
Pages3515–3519
Abstract
Isotopic labeling with 33S has been used to show that the radical obtained by photolysis of tetrasulfur tetranitride-bis(norbornene) and by the thermal reaction of tetrasulfur dinitride with norbornene is exo-1,2-norbornyl-1′,3′,2′-dithiazolidin-2′-yl. Several analogous radicals have been prepared and it is suggested that S4N4 adducts with unsaturated hydrocarbons may provide a starting point for the synthesis of compounds containing the 1,3,2-dithiazolidine ring system. © 1979 American Chemical Society.
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LanguageEnglish
Peer reviewedYes
NPARC number21276677
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