| Download | - View final version: Synthesis and characterization of mixed ruthenium/platinum μ₄-phosphinidene, phosphorus monoxide, and related clusters (PDF, 588 KiB)
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| DOI | Resolve DOI: https://doi.org/10.1021/ic0106423 |
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| Author | Search for: Scoles, Ludmila1; Search for: Yamamoto, John H.1; Search for: Brissieux, Luc1; Search for: Sterenberg, Brian T.1; Search for: Udachin, Konstantin A.1; Search for: Carty, Arthur J.1 |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | The mixed-metal cluster complexes [Ru4(CO)12Pt(CO)PPh3(4-PR)] [R = NiPr2 (1), F (3)] were formed by capping the Ru3P face of the nido clusters [Ru4(CO)13(3-PR)] with the labile Pt(0) reagent [(2-C2H4)Pt(PPh3)2]. The aminophosphinidene complex 1 undergoes acid hydrolysis to yield the PO complex [Ru4(CO)12Pt(CO)PPh3(4-PO)][H2NiPr2] (4). The fluorophosphinidene cluster 3 reacts with ethanol to form the alkoxyphosphinidene complex [Ru4(CO)12Pt(CO)PPh3(4-POEt)] (5). Comparison of spectroscopic and structural data for clusters 1, 3, 4, and 5 reveals the remarkable effects of the 4-phosphinidene and phosphorus monoxide ligands on cluster bonding. |
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| Publication date | 2001-11-21 |
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| Publisher | American Chemical Society |
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| In | |
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| Peer reviewed | Yes |
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| NPARC number | 12332907 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | aef23551-8d1a-4a77-9b26-45fa612bac39 |
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| Record created | 2009-09-10 |
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| Record modified | 2020-05-27 |
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