Electron paramagnetic resonance spectra of some radicals from O-alkyl thioesters and O-alkyl selenoesters

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/j100524a022
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  1. National Research Council Canada
FormatText
TypeArticle
Journal titleThe Journal of Physical Chemistry
ISSN0022-3654
Volume81
Issue9
Pages915–918; # of pages: 4
Abstract
EPR spectra are reported for the radicals formed by addition of CF3·, Me3Sn·, and (EtO)2PO radicals to the C=S double bond of some thioesters and to the C=Se double bond of some selenoesters. The radicals formed by addition to thioacetate, selenoacetate, and related selenoesters adopt, for steric reasons, a conformation in which the added radical is in the eclipsed position with respect to the Cα 2pz orbital. Most radicals formed by addition to thioformates and selenoformates adopt a partly staggered conformation in which the added radical lies between the eclipsed position and the Cα 2pz nodal plane.
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LanguageEnglish
Peer reviewedYes
NPARC number21276664
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Record modified2017-03-23
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