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Hydroformylation reactions with rhodium-complexed dendrimers on silica

From National Research Council Canada

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DOIResolve DOI: https://doi.org/10.1021/ja983764b
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Affiliation
  1. National Research Council Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
Polyamidoamine dendrimers, constructed on the surface of silica, were phosphonated by using diphenylphosphinomethanol, prepared in situ, and complexed to rhodium by use of [Rh(CO)â‚‚Cl]â‚‚. Excellent selectivities, favoring the branched aldehydes obtained from aryl olefins and vinyl esters, were observed by using the Rh(I) complex as the catalyst in hydroformylation reactions. The heterogeneous Rh (I) catalyst can also be recycled and reused without significant loss of selectivity or activity.
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  • JACS: Journal of the American Chemical Society 121, no. 13 (17 March 1999): 3035–3038.
LanguageEnglish
NPARC number12340945
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Record identifierb8bd64ab-50a6-4265-b0ae-969332e9e3a7
Record created2009-09-11
Record modified2020-03-20
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