| DOI | Resolve DOI: https://doi.org/10.1126/science.1120779 |
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| Author | Search for: Geβner, O.1; Search for: Lee, A. M. D.1; Search for: Shaffer, J. P.; Search for: Reisler, H.; Search for: Levchenko, S. V.; Search for: Krylov, A. I.; Search for: Underwood, Jonathan G.; Search for: Shi, H.; Search for: East, A. L. L.; Search for: Wardlaw, D. M.; Search for: Chrysostom, E. t. H.; Search for: Hayden, C. C.; Search for: Stolow, Albert1 |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | The coupled electronic and vibrational motions governing chemical processes are best viewed from the molecule's point of view--the molecular frame. Measurements made in the laboratory frame often conceal information because of the random orientations the molecule can take. We used a combination of time-resolved photoelectron spectroscopy, multidimensional coincidence imaging spectroscopy, and ab initio computation to trace a complete reactant-to-product pathway--the photodissociation of the nitric oxide dimer--from the molecule's point of view, on the femtosecond time scale. This method revealed an elusive photochemical process involving intermediate electronic configurations. |
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| Publication date | 2006-01-13 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 12338625 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | b9976623-d2ab-4869-a56e-80ab2a4b8828 |
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| Record created | 2009-09-10 |
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| Record modified | 2020-04-22 |
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