| DOI | Resolve DOI: https://doi.org/10.1039/P29730000420 |
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| Author | Search for: Ingold, K. U.1 |
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| Affiliation | - National Research Council Canada
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| Format | Text, Article |
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| Abstract | The reaction of butoxyl radicals with diborane has been shown by e.s.r. spectroscopy to yield t-butyl radicals. The rate constant for this process is given by k = 108.4 × 102.9/θ l mol -1 s-1 where θ = 2.303 RT in kcal mol-1. No intermediate 4-co-ordinate boron radical could be detected. Analogies are drawn with t-butoxyl-trialkyl phosphite reaction and with the oxidation of trialkylboranes by alkaline hydrogen peroxide and by amine oxides. t-Butyl radicals are not formed in detectable quantities in either the t-butoxyl-alkyldiborane or in the t-butoxyl-phosphine reactions. |
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| Publication date | 1973 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21276785 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | cb50bd16-0234-43b7-829e-fd026ca3f6f0 |
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| Record created | 2015-10-13 |
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| Record modified | 2020-03-13 |
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