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Permanganate oxidation of N-aryl-2-naphthylamines

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/jo01276a004
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Affiliation
  1. National Research Council of Canada
FormatText, Article
Abstract
The major crystalline products from permanganate oxidation of N-aryl-2-naphthylamines are 1,1′-coupling dimers. Structures were determined by instrumental methods and by degradation to known 7-aryldibenzo[c,g]-carbazoles. Also formed are significant quantities of carbon-nitrogen coupling products, believed to be the o-semidines. 7-Aryldibenzo[c,g]carbazoles are formed in minor amounts. No evidence was found for stable symmetrical tetraarylhydrazines.
Publication date
In
  • Journal of Organic Chemistry 33, no. 12 (1968): 4329–4332.
LanguageEnglish
Peer reviewedYes
NPARC number21276678
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