| DOI | Resolve DOI: https://doi.org/10.1103/PhysRevA.108.043113 |
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| Author | Search for: Allum, Felix; Search for: Kumagai, YoshiakiORCID identifier: https://orcid.org/0000-0002-2492-4676; Search for: Nagaya, Kiyonobu; Search for: Harries, James; Search for: Iwayama, Hiroshi; Search for: Britton, Mathew; Search for: Bucksbaum, Philip H.; Search for: Burt, Michael; Search for: Brouard, Mark; Search for: Downes-Ward, Briony; Search for: Driver, Taran; Search for: Heathcote, David; Search for: Hockett, Paul1; Search for: Howard, Andrew J.; Search for: Lee, Jason W. L.; Search for: Liu, Yusong; Search for: Kukk, Edwin; Search for: McManus, Joseph W.; Search for: Milsesevic, Dennis; Search for: Niozu, Akinobu; Search for: Niskanen, Johannes; Search for: Orr-Ewing, Andrew J.; Search for: Owada, Shigeki; Search for: Robertson, Patrick A.; Search for: Rudenko, Artem; Search for: Ueda, Kiyoshi; Search for: Unwin, James; Search for: Vallance, Claire; Search for: Walmsley, Tiffany; Search for: Minns, Russell S.; Search for: Rolles, Daniel; Search for: Ashfold, Michael N. R.; Search for: Forbes, RuaridhORCID identifier: https://orcid.org/0000-0003-2097-5991 |
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| Affiliation | - National Research Council of Canada. Quantum and Nanotechnologies
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| Funder | Search for: SLAC National Accelerator Laboratory; Search for: U.S. Department of Energy; Search for: U.S. DOE Office of Science; Search for: Basic Energy Sciences; Search for: Helmholtz Association; Search for: University of Southampton; Search for: Engineering and Physical Sciences Research Council; Search for: National Science Foundation; Search for: Academy of Finland; Search for: Japan Society for the Promotion of Science |
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| Format | Text, Article |
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| Abstract | We study ultrafast charge rearrangement in dissociating 2-iodopropane (2−C₃H₇I) using site-selective core ionization at the iodine atom. Clear signatures of electron transfer between the neutral propyl fragment and multiply charged iodine ions are observed in the recorded delay-dependent ion momentum distributions. The detected charge-transfer pathway is only favorable within a small (few angstroms), charge-state-dependent spatial window located at C-I distances longer than that of the neutral ground-state molecule. These results offer insights into the physics underpinning charge transfer in isolated molecules and pave the way for a different class of time-resolved studies. |
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| Publication date | 2023-10-23 |
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| Publisher | American Physical Society |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | d1a60e2e-0b98-4c12-bb30-f78ebd8ca55d |
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| Record created | 2024-06-18 |
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| Record modified | 2024-06-18 |
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