Kinetic applications of electron paramagnetic resonance spectroscopy. 35. The search for a dialkylaminyl rearrangement. Ring opening of N-cyclobutyl-N-n-propylaminyl

DOI	Resolve DOI: https://doi.org/10.1021/ja00521a052
Author	Search for: Maeda, Y.¹; Search for: Ingold, K. U.¹
Name affiliation	National Research Council of Canada
Format	Text, Article
Abstract	A search for a dialkylaminyl radical which rearranges at a rate suitable for study by kinetic EPR spectroscopy has shown that cyclobutyl-n-propylaminyl is such a species. This radical undergoes ring opening, and the rate constant for this process can be represented by log (kr/s-1) = (12.8 ± 1.5) - (10.5 ± 1.5)/θ, where θ = 2.3RT kcal/mol. © 1980 American Chemical Society.
Publication date	1980
In	Journal of the American Chemical Society 102, no. 1 (1980): 328–331.
Language	English
Peer reviewed	Yes
NPARC number	21276612
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Record identifier	d3e599af-b465-4e40-8ff6-dc0f422f689a
Record created	2015-10-13
Record modified	2020-03-13