Kinetic applications of electron paramagnetic resonance spectroscopy. 35. The search for a dialkylaminyl rearrangement. Ring opening of N-cyclobutyl-N-n-propylaminyl

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/ja00521a052
AuthorSearch for: 1; Search for: 1
Name affiliation
  1. National Research Council of Canada
FormatText, Article
Journal titleJournal of the American Chemical Society
ISSN0002-7863
Volume102
Issue1
Pages328–331
Abstract
A search for a dialkylaminyl radical which rearranges at a rate suitable for study by kinetic EPR spectroscopy has shown that cyclobutyl-n-propylaminyl is such a species. This radical undergoes ring opening, and the rate constant for this process can be represented by log (kr/s-1) = (12.8 ± 1.5) - (10.5 ± 1.5)/θ, where θ = 2.3RT kcal/mol. © 1980 American Chemical Society.
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LanguageEnglish
Peer reviewedYes
NPARC number21276612
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