| DOI | Resolve DOI: https://doi.org/10.1021/cm0497529S0897-4756(04)09752-2 |
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| Author | Search for: Xu, Z.; Search for: Braterman, P.; Search for: Yu, Kui1; Search for: Xu, H. (Hongyi)2; Search for: Wang, Y.; Search for: Brinker, C. |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
- National Research Council of Canada. NRC Institute for Aerospace Research
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| Format | Text, Article |
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| Abstract | We report a novel packing mode specific to the cis unsaturated hydrocarbon chain in the title compound, a self-assembled layered double hydroxide-surfactant hybrid nanomaterial, and its influence on crystallite morphology and structure. The kink imposed by the cis double bond in oleate leads to partial overlap between chains on adjacent layers, with incomplete space filling, in contrast to the more usual (and more efficient) mono- and bilayer packings exhibited by the trans analogues. Incorporation of surfactant into the growing crystallite leads to a reversal of the usual LDH growth habit and results in crystallite shapes featuring ribbonlike sheets. The thermal decomposition behavior of the as-prepared organic/inorganic nanocomposites in air and N2 is described. |
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| Publication date | 2004-07-13 |
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| In | |
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| NPARC number | 12339244 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | d6e46895-f635-46a5-bd2e-e6708b65ad48 |
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| Record created | 2009-09-11 |
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| Record modified | 2020-04-17 |
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