| Alternative title | Reaction mechanism and kinetics of lithium battery cathode materials LiNiO2 and CO2 |
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| DOI | Resolve DOI: https://doi.org/10.1016/j.jpowsour.2007.04.083 |
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| Author | Search for: Liu, Hanson; Search for: Yang, Yong; Search for: Zhang, Jiujun1 |
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| Affiliation | - National Research Council of Canada. NRC Institute for Fuel Cell Innovation
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| Format | Text, Article |
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| Subject | lithium nickel oxide; carbon dioxide; reaction mechanism; kinetics analysis; cathode material; lithium ion batteries |
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| Abstract | The reaction between LiNiO₂ and CO₂ is relevant to the synthesis and storage of LiNiO₂-based cathode materials for lithium ion batteries. In this work, this reaction was investigated in pure CO₂ atmosphere at both room and high temperatures. The reaction products (Li₂CO₃, NiO, and O₂) and activation energies were determined by means of XRD, XPS, MS and TGA techniques. The reaction mechanism was explored in an effort to clarify some inconsistencies in the previous works. Kinetics analysis was also carried out to understand the reaction process relevant to the synthesis and storage of LiNiO₂ cathode material. |
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| Publication date | 2007-11 |
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| Publisher | Elsevier |
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| In | |
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| Peer reviewed | Yes |
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| NPARC number | 8900918 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | d8cef751-7a8a-4147-8dad-d2b73cc55344 |
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| Record created | 2009-04-22 |
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| Record modified | 2023-06-26 |
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