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Photochemistry of 1-benzoyl-2,2-dialkylcyclopropanes. Importance of conformational effects on biradical lifetimes

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1016/0009-2614(86)85062-X
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Affiliation
  1. National Research Council Canada
FormatText, Article
Abstract
Conformationally locked 1,4-biradicals generated in the Norrish type II reaction of 1-benzoyl-2,2-diethylcyclopropane have lifetimes of 22-4 ns. This lifetime is much shorter than those observed for conformationally mobile biradicals; the difference is attributed to increased end-to-end interaction.
Publication date
In
  • Chemical Physics Letters 124, no. 6 (14 March 1986): 493–498.
LanguageEnglish
NRC numberNRCC 24990
NPARC number12328938
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Record identifierd966d58e-3ba4-4d00-9691-6676f335b6b0
Record created2009-09-10
Record modified2020-03-17
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