| Download | - View accepted manuscript: Platinum nanoparticles supported on ionic liquid-modified magnetic nanoparticles : Selective hydrogenation catalysts (PDF, 702 KiB)
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| DOI | Resolve DOI: https://doi.org/10.1002/adsc.200700129 |
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| Author | Search for: Abu-Reziq, Raed; Search for: Wang, Dashan1; Search for: Post, Michael1; Search for: Alper, Howard |
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| Affiliation | - National Research Council of Canada. NRC Institute for Chemical Process and Environmental Technology
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| Format | Text, Article |
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| Subject | Alkynes; Chemoselectivity; Hydrogenation' Magnetic nanoparticles; Platinum; α,β-unsaturated aldehydes |
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| Abstract | A method for supporting platinum nanoparticles on magnetite nanoparticles is described. The method requires modification of the surface of the magnetic nanoparticles with ionic liquid groups. Before modification, the magnetic nanoparticles are not stable and easilyaggrega te and, after modification, the magnetite nanoparticles become highly stable and soluble in polar or non-polar organic solvents depending on the alkyl group of the linked ionic liquids. The supporting of platinum nanoparticles on the modified magnetic nanoparticles was achieved byadsorb ing platinum salts (K₂PtCl₄) on the surface of the magnetite nanoparticles via ion exchange with the linked ionic liquid groups and then reducing them byhy drazine. The supported platinum nanoparticles were applied in the catalytic hydrogenation of alkynes in which cis-alkenes were selectivelyproduce d, and in the hydrogenation of α,β-unsaturated aldehydes where the allyl alcohols were obtained as the exclusive products. The new catalyst can be easilysep arated from the reaction mixtures by applying an external magnetic field and recycled. |
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| Publication date | 2007-09-06 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NRC number | NRCC 52160 |
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| NPARC number | 15550757 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | e009e318-b5c3-4ee8-9eea-96c2e5448c8d |
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| Record created | 2010-06-10 |
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| Record modified | 2020-05-10 |
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