| DOI | Resolve DOI: https://doi.org/10.1126/science.abf1656 |
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| Author | Search for: Zinchenko, Kristina S.ORCID identifier: https://orcid.org/0000-0002-2440-3811; Search for: Ardana-Lamas, FernandoORCID identifier: https://orcid.org/0000-0001-9028-5051; Search for: Seidu, Issaka1ORCID identifier: https://orcid.org/0000-0002-9815-0132; Search for: Neville, Simon P.1ORCID identifier: https://orcid.org/0000-0001-8134-1883; Search for: Van Der Veen, Joscelyn1ORCID identifier: https://orcid.org/0000-0002-9407-6449; Search for: Lanfaloni, Valentina UtrioORCID identifier: https://orcid.org/0000-0002-5390-3065; Search for: Schuurman, Michael S.1ORCID identifier: https://orcid.org/0000-0002-0922-9034; Search for: Wörner, Hans JakobORCID identifier: https://orcid.org/0000-0002-8877-0872 |
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| Affiliation | - National Research Council of Canada. Security and Disruptive Technologies
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| Format | Text, Article |
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| Abstract | Conical intersections allow electronically excited molecules to return to their electronic ground state. Here, we observe the fastest electronic relaxation dynamics measured to date by extending attosecond transient-absorption spectroscopy (ATAS) to the carbon K-edge. We selectively launch wave packets in the two lowest electronic states (D₀ and D₁) of C₂H₄⁺. The electronic D₁ → D₀ relaxation takes place with a short time constant of 6.8 ± 0.2 femtoseconds. The electronic-state switching is directly visualized in ATAS owing to a spectral separation of the D₁ and D₀ bands caused by electron correlation. Multidimensional structural dynamics of the molecule are simultaneously observed. Our results demonstrate the capability to resolve the fastest electronic and structural dynamics in the broad class of organic molecules. They show that electronic relaxation in the prototypical organic chromophore can take place within less than a single vibrational period. |
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| Publication date | 2021-01-29 |
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| Publisher | American Association for the Advancement of Science |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | ec16270e-1d82-41ec-85f8-1240cac058e6 |
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| Record created | 2021-06-30 |
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| Record modified | 2021-07-02 |
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