| DOI | Resolve DOI: https://doi.org/10.1016/0040-4020(96)00742-9 |
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| Author | Search for: Avila, D.V; Search for: Ingold, K. U.1; Search for: Lusztyk, J; Search for: Dolbier Jr., W.R; Search for: Pan, H.-Q |
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| Affiliation | - National Research Council of Canada
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| Format | Text, Article |
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| Subject | alkene derivative; chemical reaction kinetics; drug synthesis; reaction analysis; technique |
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| Abstract | Absolute rate constants for (CF3)3C. addition to terminal olefins increase by roughly a factor of 30 for every 1 eV decrease in the ionization potential (IP) of the alkene. A similar decrease in IP increases the rate of addition of CF3. and n-C3F7. by a factor of only 3 or 4. The perfluoro-tert-butyl radical is, therefore, the most electrophilic, neutral carbon-centered radical to have been studied to date. |
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| Publication date | 1996 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21276492 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | f5d9de9f-8294-404b-b2bc-6f17d77ba88a |
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| Record created | 2015-10-13 |
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| Record modified | 2020-03-20 |
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