| Téléchargement | - Voir la version finale : Calibration model averaging in chemical analysis: a case study for the method of standard additions (PDF, 780 Kio)
- Voir les données supplémentaires : Calibration model averaging in chemical analysis: a case study for the method of standard additions (PDF, 1.7 Mio)
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| DOI | Trouver le DOI : https://doi.org/10.1088/1681-7575/accd75 |
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| Auteur | Rechercher : Pagliano, Enea1Identifiant ORCID : https://orcid.org/0000-0001-9755-8737; Rechercher : Meija, Juris1Identifiant ORCID : https://orcid.org/0000-0002-3349-5535 |
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| Affiliation | - Conseil national de recherches du Canada. Centre de recherche en métrologie
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| Format | Texte, Article |
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| Sujet | method of standard additions; uncertainty evaluation; model averaging |
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| Résumé | In this study we demonstrate that the method of standard additions can provide unreliable results in chemical analysis when the linear calibration model is forced to fit the data. A well designed standard addition experiment can still yield results biased by 10% when the analyst relies only on the linear model. Recently, the Joint Committee for Guides in Metrology (GUM-6) has emphasized the need to address the uncertainty inherent to the choice of measurement models and here we show how model averaging can provide a practical way to account for model uncertainty in the method of standard additions. |
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| Date de publication | 2023-05-11 |
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| Maison d’édition | IOP Publishing |
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| Licence | |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 035380be-0529-44b8-a20c-e7ceb31f846b |
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| Enregistrement créé | 2024-01-25 |
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| Enregistrement modifié | 2024-01-25 |
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