DOI | Trouver le DOI : https://doi.org/10.1016/j.apsusc.2014.04.077 |
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Auteur | Rechercher : Siddaramanna, Ashoka; Rechercher : Saleema, N.1; Rechercher : Sarkar, D. K. |
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Affiliation | - Conseil national de recherches du Canada. Automobile et les transports de surface
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Format | Texte, Article |
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Sujet | Electrodeposition; Ordered polypyrrole; X-ray diffraction; Infrared spectroscopy; Copper films; Aluminium alloy surface |
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Résumé | Fabrication of highly ordered conducting polymers on metal surfaces has received a significant interest owing to their potential applications in organic electronic devices. In this context, we have developed a simple method for the synthesis of highly ordered polypyrrole (PPy) on copper modified aluminium surfaces via electrochemical polymerization process. A series of characteristic peaks of PPy evidenced on the infrared spectra of these surfaces confirm the formation of PPy. The X-ray diffraction (XRD) pattern of PPy deposited on copper modified aluminium surfaces also confirmed the deposition of PPy as a sharp and intense peak at 2θ angle of 23° attributable to PPy is observed while this peak is absent on PPy deposited on as-received aluminium surfaces. An atomic model of the interface of PPy/Cu has been presented based on the inter-atomic distance of copper-copper of (1 0 0) plane and the inter-monomer distance of PPy, to describe the ordering of PPy on Cu modified Al surfaces. |
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Date de publication | 2014-04-13 |
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Dans | |
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Langue | anglais |
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Publications évaluées par des pairs | Oui |
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Numéro NPARC | 21272844 |
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Exporter la notice | Exporter en format RIS |
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Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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Identificateur de l’enregistrement | 0ee500df-fed8-440a-b5f9-ee0ebcbaf98e |
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Enregistrement créé | 2014-12-03 |
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Enregistrement modifié | 2020-04-22 |
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