Téléchargement | - Voir le manuscrit accepté : Low temperature solid oxide fuel cells with pulsed laser deposited bi-layer electrolyte (PDF, 1.5 Mio)
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DOI | Trouver le DOI : https://doi.org/10.1016/j.jpowsour.2006.09.102 |
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Auteur | Rechercher : Yang, Dongfang1; Rechercher : Zhang, Xinge2; Rechercher : Nikumb, Suwas1; Rechercher : Decès-Petit, Cyrille2; Rechercher : Hui, Rob2; Rechercher : Maric, Radenka2; Rechercher : Ghosh, Dave2 |
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Affiliation | - Conseil national de recherches du Canada. Institut des matériaux industriels du CNRC
- Conseil national de recherches du Canada. Institut d'innovation en piles à combustible du CNRC
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Format | Texte, Article |
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Sujet | SOFC; low temperature; SDC; ScSZ; bi-layer electrolyte; pulsed laser deposition |
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Résumé | Solid oxide fuel cells (SOFC) using a pulsed laser deposited bi-layer electrolyte have been successfully fabricated and have shown very good performance at low operating temperatures. The cell reaches power densities of 0.5 W cm−2 at 550 °C and 0.9 W cm−2 at 600 °C, with open circuit voltage (OCV) values larger than 1.04 V. The bi-layer electrolyte contains a 6–7 μm thick samarium-doped ceria (SDC) layer deposited over a ∼1 μm thick scandium-stabilized zirconia (ScSZ) layer. The electrical leaking between the anode and cathode through the SDC electrolyte, which due to the reduction of Ce4+ to Ce3+ in reducing environment when using a single layer SDC electrolyte, has been eliminated by adopting the bi-layer electrolyte concept. Both ScSZ and SDC layers in the bi-layer electrolyte prepared by the pulsed laser deposition (PLD) technique are the highly conductive cubic phases. Poor conductive (Zr, Ce)O2-based solid solutions or β-phase ScSZ were not found in the bi-layer electrolyte prepared by the PLD due to low processing temperatures of the technique. Excellent reliability and flexibility of the PLD technique makes it a very promising technique for the fabrication of thin electrolyte layer for SOFCs operating at reduced temperatures. |
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Date de publication | 2006-11 |
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Dans | |
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Langue | anglais |
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Publications évaluées par des pairs | Oui |
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Numéro NPARC | 21274296 |
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Exporter la notice | Exporter en format RIS |
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Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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Identificateur de l’enregistrement | 1fdc94b0-198b-44b0-9c07-4820148baabb |
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Enregistrement créé | 2015-03-09 |
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Enregistrement modifié | 2020-06-04 |
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