| Résumé | A novel approach to the generation of volatile iron compounds (likely the pentacarbonyl) with high efficiency is described, wherein solutions containing either Fe2+ or Fe3+ and low molecular weight organic acids such as formic, acetic or propionic are exposed to a UV source. An optimum generation efficiency of 60 ± 2% was achieved in 50% formic acid at pH 2.5 with an irradiation time of 250 s by use of a 17 W low-pressure mercury grid lamp. Compared to conventional solution nebulization, sensitivity and limit of detection were improved 80- and 100-fold, respectively, at the 238.204 nm Fe II emission line. A precision of 0.75% RSD was achieved at a concentration of 100 ng/mL. Photochemical vapor generation sample introduction was used for the determination of trace iron in several environmental Certified Reference Materials, including National Research Council Canada DORM-3 fish muscle tissue, DOLT-3 and DOLT-4 fish liver tissues, and SLRS-5 river water, providing analytical results in excellent agreement with certified values based on a simple external calibration. |
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