| Résumé | The formation and characterization of various types of organically modified C -S -H-based nanocomposites have recently been investigated. The engineering properties of this class of cementitious materials, however, have rarely been studied. The current work examines a new approach to the assessment of the mechanical performance of C -S -H/polyaniline nanocomposites prepared in situ using C -S -H systems having C/S ratios of 0.8 and 1.2. Test methods including X-ray diffraction and dynamic mechanical analysis were employed in order to evaluate the physical and mechanical stability of these polymer-modified C -S -H nanocomposites. The variations in the 002 basal spacing, storage modulus (E′) and internal friction (tan δ) of the C -S -H/polyaniline nanocomposites were examined upon the incremental removal of the interlayer water. It was suggested that the polyaniline molecules may reinforce the C -S -H lamellar structure as indicated by the magnitude of the decrease in the 002 basal-spacing during the dehydration. Moreover, the initial DMA response of the C -S -H/polyaniline nanocomposites appears to be improved. © 2013 RILEM. |
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