| DOI | Trouver le DOI : https://doi.org/10.1016/j.ssnmr.2016.12.006 |
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| Auteur | Rechercher : Brinkmann, Andreas1; Rechercher : O’dell, Luke A. |
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| Affiliation | - Conseil national de recherches du Canada. Science des mesures et étalons
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| Format | Texte, Article |
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| Sujet | 14N solid-state NMR; overtone spectroscopy; excitation pulses; WURST pulses; composite pulses |
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| Résumé | Numerically exact simulations of the 14N overtone (14NOT) MAS NMR experiment are used to investigate the effects of the applied magnetic field strength as well as three types of excitation pulse. The results show that both the resolution and sensitivity of 14NOT MAS NMR increase linearly with the applied static magnetic field strength. Standard RF excitation pulses are compared with frequency-swept WURST pulses as well as several composite pulses. WURST pulses are demonstrated to provide the largest bandwidths, while the direction of the frequency sweep is shown to be important when these pulses are used for the direct observation of 14NOT signals. A composite pulse is shown to provide the most efficient excitation overall, but only when applied on resonance. WURST excitation pulses are therefore the best option when studying a sample with unknown 14N NMR parameters. |
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| Date de publication | 2017-07 |
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| Maison d’édition | Elsevier |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 23003246 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 9094f1c7-edc7-43f8-a711-e6ecd876b920 |
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| Enregistrement créé | 2018-05-09 |
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| Enregistrement modifié | 2020-03-16 |
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