| Téléchargement | - Voir le manuscrit accepté : Surface and bulk analysis of the oxidation of polyolefins (PDF, 1.2 Mio)
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| Auteur | Rechercher : Lacoste, J.; Rechercher : Deslandes, Y.1; Rechercher : Black, P.1; Rechercher : Carlsson, D. J.1 |
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| Affiliation | - Conseil national de recherches du Canada. Institut de technologie des procédés chimiques et de l'environnement du CNRC
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| Format | Texte, Article |
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| Résumé | The non-uniformity of oxidation across polypropylene and polyethylene films has been measured by a combination of X-ray photoelectron spectroscopy (XPS), internal reflection infrared spectroscopy and bulk property measurements. Films were photo-oxidized or -y-irradiated in air. Photo-oxidized film showed detectable oxidation at a very early stage in the outermost 70 A of the film thickness (as measured by XPS). Oxidation advanced into the lilms as exposure level increased. Although y-irradiated films also showed enhanced surface oxidation, this was attributed to the reaction of the polymer surfaces with short-lived species such as ozone from the radiolysis of the moist air atmosphere. When films were -y-irradiated and oxidized under conditions which precluded these reactions. oxidation proceeded uniformly throughout the film cross-section. |
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| Date de publication | 1995 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro du CNRC | NRCC 51931 |
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| Numéro NPARC | 16020203 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 9898056f-b846-4c3e-88ae-54eef64a3a21 |
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| Enregistrement créé | 2010-09-02 |
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| Enregistrement modifié | 2020-04-29 |
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