| Résumé | Bound state rovibrational energy level calculations using a high-level intermolecular potential surface are reported for H₂O–CO and D₂O–CO. They predict the ground K = 1 levels to lie about 20 (12) cm⁻¹ above K = 0 for H₂O–CO (D₂O–CO) in good agreement with past experiments. But the first excited K = 1 levels are predicted to lie about 3 cm−1 below their K = 0 counterparts in both cases. Line strength calculations also indicate that mid-infrared transitions from the K = 0 ground state to this seemingly anomalous excited K = 1 state should be observable. These predictions are strikingly verified by new spectroscopic measurements covering the C–O stretch region around 2200 cm−1 for H₂O–CO, D₂O–CO, and HOD–CO, and the O–D stretch region around 2700 cm−1 for D₂O–CO, HOD–CO, and DOH–CO. The experiments probe a pulsed supersonic slit jet expansion using tunable infrared quantum cascade laser or optical parametric oscillator sources. Discrete perturbations in the O–D stretch region give an experimental lower limit to the binding energy D₀ of about 340 cm−1 for D₂O–CO, as compared to our calculated value of 368 cm−1. Wavefunction plots are presented to help understand the intermolecular dynamics of H₂O–CO. Coriolis interactions are invoked to explain the seemingly anomalous energies of the first excited K = 1 levels. |
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