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Highly efficient thieno[3,4-c]pyrrole-4,6-dione-based solar cells processed from non-chlorinated solvent

Par Conseil national de recherches du Canada

DOITrouver le DOI : https://doi.org/10.1016/j.orgel.2013.12.012
AuteurRechercher : 1; Rechercher : ; Rechercher : ; Rechercher : 1
Affiliation
  1. Conseil national de recherches du Canada
FormatTexte, Article
SujetBulk heterojunction; Bulk heterojunction organic solar cells; Large-scale applications; Non-chlorinated solvents; Polymer Solar Cells; Polymeric solar cells; Power conversion efficiencies; Thieno[3,4-c]pyrrole-4,6-dione; Additives; Aromatic compounds; Carbon inorganic compounds; Heterojunctions; Naphthalene; Polymers; Solar cells; Solvents; Nanostructured materials
Résumé
To obtain high performance bulk heterojunction organic solar cells, the selection of solvents to prepare the donor/acceptor blend is as important as the choice of the donor/acceptor materials themselves. State-of-the-art lab-scale polymer solar cells have evolved around chlorinated solvents such as chloroform, chlorobenzene and o-dichlorobenzene. However, for large scale applications, benign processing solvents may become inevitable. In this work, we used a mixture of Xylenes (a chlorine-free solvent), methyl naphthalene (MeN) and 1,8-diiodoctane (DIO) to modulate the nano-scale morphology of poly(4,4-bis(2-ethylhexyl)-dithieno[3,2-b:2′,3′-d]silole-alt-1, 3-(5-octylthieno[3,4-c]pyrrole-4,6-dione) (PDTSTPD)/PCBM blend, one of the most efficient active layer in polymeric solar cell. Power conversion efficiencies up to 5.5% (with PC61BM) and 6.2% (with PC71BM) were obtained for photovoltaic devices with an active area of 1.0 cm2. © 2013 Elsevier B.V. All rights reserved.
Date de publication
Dans
  • Organic Electronics: physics, materials, applications 15, nº 2 (2014) : 543–548.
Langueanglais
Publications évaluées par des pairsOui
Numéro NPARC21270841
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Identificateur de l’enregistrementa5d11107-59eb-475c-a689-f97d6913e010
Enregistrement créé2014-02-17
Enregistrement modifié2020-04-22
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