Téléchargement | - Sera disponible ici le 11 avril 2025
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DOI | Trouver le DOI : https://doi.org/10.1021/acsami.4c01105 |
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Auteur | Rechercher : Whittingham, Alexander W. H.1Identifiant ORCID : https://orcid.org/0000-0001-9752-6356; Rechercher : Boke, Marlyn; Rechercher : Smith, Rodney D. L.Identifiant ORCID : https://orcid.org/0000-0003-1209-9653 |
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Affiliation | - Conseil national de recherches du Canada. Innovations dans les énergies propres
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Bailleur de fonds | Rechercher : Ontario Research Foundation; Rechercher : Natural Sciences and Engineering Research Council of Canada |
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Format | Texte, Article |
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Sujet | perovskite; oxygen reduction reaction; reaction mechanism; electrocatalysis; peroxide production; lattice distortions |
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Résumé | Compositional tuning of layered perovskite oxidesprovides a means of systematically studying how local distortionsaffect fundamental aspects of electrochemical reaction pathways.Structural analysis of a family of samples La₁.₂Sr₀.₈Ni₁₋yCoyO₄ showsthat Ni-rich compositions have an expanded crystalline c axis, which isanisotropically compressed by systematic Co incorporation. Ramanspectra reveal the strong growth of a symmetry forbidden mode,which suggests that Co acts through localized distortions. Crystallo-graphic and spectroscopic parameters describing this structuraldistortion correlate to the measured Tafel slopes for the oxygenreduction reaction for all Ni-containing samples, which is attributedto the distortion of potential energy surfaces by the Jahn−Tellerexpansion of d⁷ Ni(III) cations. Incorporation of Co not only minimizes the distortion but alters the apparent selectivity of theoxygen reduction reaction away from H₂O₂ and toward H₂O. Rotating ring-disk electrochemical measurements, however, indicatethat the apparent change in selectivity is due to activation of a first-order chemical disproportionation of H₂O₂ that is activated byCo in the lattice. These outcomes will support efforts to design electrocatalysts and reactors for the electrochemical synthesis ofH₂O₂. |
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Date de publication | 2024-04-11 |
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Maison d’édition | American Chemical Society |
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Licence | |
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Dans | |
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Langue | anglais |
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Sous presse | Oui |
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Publications évaluées par des pairs | Oui |
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Exporter la notice | Exporter en format RIS |
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Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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Identificateur de l’enregistrement | ae1e497c-0118-4c5c-bbdd-46a02121b9a2 |
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Enregistrement créé | 2024-05-15 |
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Enregistrement modifié | 2024-05-16 |
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